プレスリリース Press Releases

理論の力で発見：過酸化水素合成のための高効率電極触媒（英語版のみ）

Hydrogen peroxide (H₂O₂) is an industrially important chemical with versatile applications. However, the traditional method used to produce H₂O₂ is energy intensive and produces significant emissions.

As a means to achieve sustainable development, scientists have sought to synthesize H₂O₂ electrochemically. This can be done via the oxygen reduction reactions catalyzed by a single cobalt-nitrogen-carbon (Co-N-C) catalyst. But tailoring the precise catalyst atomic structure has been a struggle.

Now, an international group of researchers has theoretically designed a Co-N-C catalyst with unique structures for high-performing electrochemical H₂O₂ synthesis. The group successfully verified their prediction after experimentally implementing the synthesis, analyzing its characterizations, and carrying-out catalytic tests.

Details of their findings were published in the journal Energy & Environmental Science.

“To date, the search for a catalyst has been carried out based on exhaustive trial-and-error experiments,” says Hao Li, associate professor at Tohoku University's Advanced Institute for Materials Research (WPI-AIMR) and corresponding author of the paper. “Our discovery showed that theory-guided research can provide precise design guidelines for catalytic experiments, saving time, money, and human resources.”

The group comprised researchers from Japan, Australia, Canada, and China. In particular, Li and his colleague and fellow corresponding author, Li Wei, received support from the University of Sydney under the international SDG-Collaboration Program, a program that promotes international collaboration on SDG-related research between the University of Sydney and other universities.

To address the stumbling block of H₂O₂, the researchers constructed a heterogenous molecular catalyst from cobalt porphyrins absorbed on a carbon nanotube substrate. Their initial calculations suggested that porphyrin β-substituents and the carbon substrate could synergistically modulate Co properties and catalytic activity.

They further predicted the optimality of an octafluoro-substituted catalyst and validated their predictions through experiments, with it exhibiting >94% H₂O₂ selectivity and a high turnover frequency of 3.51 per second at an overpotential of 200 millivolts in an acid electrolyte. Furthermore, it reached a maximum H₂O₂ productivity of 10.76 mol_H2O2 g_cat⁻¹ h⁻¹ in a two-electrode electrolyzer, delivering pure H₂O₂ solutions that can be used directly for water treatment and chemical production.

Looking ahead, Li hopes to design further Co-N-C catalysts. “By tuning the type of metal center and their coordination environments, and through extensive performance and stability testing, we hope to uncover more metal-N-C for use in various electrocatalysis.”

論文情報

論文タイトル：	Heterogeneous molecular Co–N–C catalysts for efficient electrochemical H2O2 synthesis
雑誌名：	Energy & Environmental Science
著者：	Chang Liu, Zixun Yu, Fangxin She, Jiaxiang Chen, Fangzhou Liu, Jiangtao Qu, Julie M. Cairney, Chongchong Wu, Kailong Liu, Weijie Yang, Huiling Zheng, Yuan Chen*, Hao Li* (Corresponding Author), and Li Wei*
DOI番号：	10.1039/D2EE02734H

問い合わせ先

研究に関すること

報道に関すること